This study provides new insights into the complex interactions between nanoparticles. Disjoining pressures that are positive correspond to the adsorbed films. Spreading of nanofluids driven by the structural disjoining pressure gradient. A positive disjoining pressure \pi corresponds to spreading of the liquid. This paper presents the results of imbibition tests using a reservoir crude oil and a reservoir brine solution with a high salinity and a suitable nanofluid that displaces crude oil from berea sandstone waterwet and singleglass capillaries. The illinois institute of technology iit nanofluid is specially formulated to survive in a highsalinity environment and is found to result in an. Pdf nanofluids composed of liquid suspensions of nanoparticles may soon permit. Prior work performed in our laboratory on the spreading of a nanofluid on a solid substrate has revealed that the structural disjoining pressure gradient caused by the layering of the nanoparticles normal to the confining plane of the film with the wedge profile is a new mechanism for oily soil. Here, we present our experimental observations and the. Wetting and spreading of nanofluids on solid surfaces. Investigating the application of nano particles for. For two flat and parallel surfaces, the value of the disjoining pressure i. Structural disjoining pressure induced solid particle. Spreading of nanoflulds driven by the structural disjoining pressure.
However, nanofluid spreading or wetting is enhanced by the structural disjoining pressure because of the ordering of the nanoparticles. Toward a mechanistic understanding of wettability alteration in. One physical example of a disjoining pressure helps make this clearer is the case of a surface sandwiched between two parallel plates. Nanocapillarity and liquid bridgemediated force between. Request pdf spreading of nanoflulds driven by the structural disjoining. Disjoining pressure disjoining pressure is defined as the attractive and repulsive forces between two thin layer of fluid surfaces. The first part of this paper addresses studies about the major eor mechanisms of nanoparticles used in the forms of nanofluids, nanoemulsions and nanocatalysts, including disjoining pressure. Effect of nanoparticles on spontaneous imbibition of water. Nanofluids comprising nanoparticle suspensions in liquids have significant industrial applications. Wetting and spreading of nanofluids on solid surfaces driven by. Pdf enhanced oil recovery eor driven by nanofilm structural. Disjoining pressure and the energy of thin films softmatter. Enhanced oil recovery eor using nanoparticle dispersions.
The wetting and spreading of nanofluids composed of liquid suspensions of nanoparticles have significant technological applications. This paper discusses the role of the structural disjoining pressure exerted by nanoparticles on the spreading of a liquid film containing these particles. Suppose one had stacked two parallel plates separated by a distance h apart filled with a thin material. Recent studies have revealed that, compared to the spreading of base liquids without nanoparticles, the spreading of wetting nanofluids on solid surfaces is enhanced by the structural disjoining pressure. We also differentiate between the disjoining pressure mechanism and diffusion of silica nanoparticles through the oil phase by testing the attachment of. The origin of the structural disjoining pressure in a confined geometry is due to the layering. This can be achieved by the structural disjoining pressure employed by nanoparticles on the spreading of a liquid film containing these particles on the rock surface 6. The disjoining pressure was defined at mechanical equilibrium by derjaguin and.
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